Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
4-(Chloromethyl)-2,2-dimethyl-1,3-dioxolane → 4-(Azidomethyl)-2,2-dimethyl-1,3-dioxolane
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 4-(Chloromethyl)-2,2-dimethyl-1,3-dioxolane | HCID 20374 | — |
| 반응물 | Sodium Azide | HCID 33557 | — |
| 용매 | Dimethylformamide | HCID 6228 | — |
| 생성물 | 4-(Azidomethyl)-2,2-dimethyl-1,3-dioxolane | HCID 11535602 | — |
반응 단계
15.05 g. of 2,2-dimethyl-4-chloromethyl-1,3-dioxolane is dissolved in 100 ml. DMF and 6.5 g. of NaN3 are added. The mixture is stirred at 50° overnight, cooled to room temperature, diluted with 300 ml. C6H6 and washed 5 times with water. The organic phase is dried and evaporated under reduced pressure to give 2,2-dimethyl-4-azidomethyl-1,3-dioxolane.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04957912 |
| 출처 데이터셋 | uspto-grants-1990_09 |
| ORD ID | ord-322a5de2c9ca4d35ab95d469a423d030 |
| 출처 메모 | uspto-grants-1990_09 |