Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
1-(3-Benzyloxy-4-nitrophenyl)-2-dimethylaminoethene → (3-Benzyloxy-4-nitrophenyl)acetonitrile
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 1-(3-Benzyloxy-4-nitrophenyl)-2-dimethylaminoethene | HCID 54049086 | — |
| 용매 | Water | HCID 962 | — |
| 생성물 | (3-Benzyloxy-4-nitrophenyl)acetonitrile | HCID 13629306 | 45.8% |
반응 단계
18.7 g of N-[2-(3-benzyloxy-4-nitrophenyl)ethenyl]-N,N-dimethylamine and 21.3 g of hydroxylamineorthosulfonic acid in 420 ml of water are stirred for 3 days at room temperature. The thus-separated solid product is chromatographed on silica gel with cyclohexane/acetic acid (1:1), thus obtaining 7.7 g of (3-benzyloxy-4-nitrophenyl)acetonitrile, mp 73°-85° C.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04958026 |
| 출처 데이터셋 | uspto-grants-1990_09 |
| ORD ID | ord-22bb6ba83c244b488df30ab3579dde84 |
| 출처 메모 | uspto-grants-1990_09 |