참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | 9,10-Dihydroanthracene | HCID 11940 | — |
| 반응물 | Tetracyano-1,4-benzoquinone | HCID 10910733 | — |
| 용매 | Acetonitrile | HCID 6342 | — |
| 생성물 | Anthracene | HCID 8418 | — |
| 생성물 | Tetracyano-1,4-benzoquinone | HCID 10910733 | — |
반응 단계
A solution of 9,10-dihydroanthracene (35 mg; 0.192 mmol) dissolved in 1 mL dry acetonitrile was reacted with tetracyano-1,4-benzoquinone (40 mg; 0.192 mmol) also dissolved in 1 mL dry acetonitrile. After reducing the volume in half and cooling to -20° C. crystals precipitated and were collected. The infrared spectra of the precipitate was identical to that obtained from a mixture of authentic anthracene and tetracyano-1,4-hydroquinone (ν(C≡N)=2239 and 2263 cm-1) verifying that tetracyano-1,4-benzoquinone dehydrogenates 9,10-dihydroanthracene.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US05310957 |
|---|
| 출처 데이터셋 | uspto-grants-1994_05 |
|---|
| ORD ID | ord-066e79c4e71f45b3bffeac34eb7cd748 |
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| 출처 메모 | uspto-grants-1994_05 |
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