Water → 2-Benzyl-3-(tert-butylsulfonyl)propanoic acid
반응식
[CH2:1]([CH:8]([CH2:12]C(C)(C)C)[C:9]([OH:11])=S)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[S:17]([O-:22])(O[O-])(=O)=[O:18].[K+].[K+].[OH2:25]>CO>[CH2:1]([CH:8]([CH2:12][S:17]([C:2]([CH3:7])([CH3:3])[CH3:1])(=[O:22])=[O:18])[C:9]([OH:11])=[O:25])[C:2]1[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=1참가 물질
5
실험 절차
280 mg of 2-benzyl-3-tert.-butylthio-propionic acid was dissolved in 5 ml of methanol and, while cooling with ice, 1 g of potassium peroxomonosulfate in 4 ml of water was added and the whole was stirred overnight at room temperature. The solution was diluted with water and extracted with methylene chloride, and the extracts were dried and concentrated by evaporation (260 mg, 82% yield).
후처리
- additionwas added
- extractionextracted with methylene chloride
- customthe extracts were dried
- concentrationconcentrated by evaporation (260 mg, 82% yield)
출처 및 근거
- ORD 기록
- ord-c3793910c873424581c865efc9faa699
- 출처 데이터셋
- uspto-grants-1994_05
- 특허 번호
- US05317039
반응 노트
불러오는 중…