Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
HRID 1039985생성일: 2026년 10월 25일
2-(Trimethylsiloxy)-1,3-butadiene → Ethyl 7-[(trimethylsilyl)oxy]spiro[2.5]oct-6-ene-4-carboxylate
https://huagongshe.com/reaction/1039985
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | 2-(Trimethylsiloxy)-1,3-butadiene | HCID 554657 | — |
| 반응물 | Ethyl cyclopropylideneacetate | HCID 11040705 | — |
| 용매 | Toluene | HCID 1140 | — |
| 생성물 | Ethyl 7-[(trimethylsilyl)oxy]spiro[2.5]oct-6-ene-4-carboxylate | HCID 67249603 | — |
반응 단계
2-(Trimethylsiloxy)-1,3-butadiene (900 mg, 6.33 mmol) and ethyl cyclopropylideneacetate (2195 mg, 17.40 mmol) were combined in toluene (3 ml) and heated to 130° C. for 14 h. The mixture was then allowed to cool to room temperature and concentrated in vacuo to yield ethyl 7-[(trimethylsilyl)oxy]spiro[2.5]oct-6-ene-4-carboxylate that was used without further purification in the subsequent reaction.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| 특허 번호 | US08551984B2 |
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| 출처 데이터셋 | uspto-grants-2013_10 |
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| ORD ID | ord-74b083bd23a040c68d51c16314ae840d |
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| 출처 메모 | uspto-grants-2013_10 |
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