1-Methylimidazole → HCID 86647249, 화합물

HRID 1043394노트

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HRID 1043394 반응식
[CH3:1][N:2]1[CH:6]=[CH:5][N:4]=[CH:3]1.[I:7][CH2:8][CH2:9][CH2:10][Si:11]([O:16][CH3:17])([O:14][CH3:15])[O:12][CH3:13]>>[I-:7].[CH3:1][N+:2]1[CH:6]=[CH:5][N:4]([CH2:8][CH2:9][CH2:10][Si:11]([O:16][CH3:17])([O:14][CH3:15])[O:12][CH3:13])[CH:3]=1

참가 물질

3

반응물 2

HCID 13901-MethylimidazoleHCID 2759373(3-Iodopropyl)trimethoxysilane

생성물 1

HCID 86647249HCID 86647249, 화합물

반응 조건

온도
114 °C

실험 절차

N-Methylimidazole (156.8 g; 1.91 mol) and 3-iodopropyltrimethoxysilane (569.8 g; 1.96 mol) were charged to a 1 L, 3-necked flask to form a reaction mixture. The reaction mixture was heated to 114° C. for eight hours during which time the color of the mixture changed from pale yellow to green and then to black. The crude reaction product was washed twice with 80 mL of toluene (2×40 mL). The resulting black oily liquid of N-methyl-N′-(3-trimethoxysilylpropyl) imidazolium iodide was dissolved in 286 g of methylene chloride and maintained as a solution.

후처리

  1. customto form a reaction mixture
  2. customThe crude reaction product
  3. washwas washed twice with 80 mL of toluene (2×40 mL)
  4. dissolutionThe resulting black oily liquid of N-methyl-N′-(3-trimethoxysilylpropyl) imidazolium iodide was dissolved in 286 g of methylene chloride
  5. temperaturemaintained as a solution

출처 및 근거

ORD 기록
ord-42adac45bab34de1a98c8045eb286cf2
출처 데이터셋
uspto-grants-2013_10
특허 번호
US08563459B2

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