Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Tributylamine → Tributyl ammonium pyrophosphate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Tributylamine | HCID 7622 | — |
| 반응물 | Sodium pyrophosphate decahydrate | HCID 3084150 | — |
| 용매 | Methanol | HCID 887 | — |
| 용매 | Water | HCID 962 | — |
| 용매 | Pyridinium | HCID 4989215 | — |
| 생성물 | Tributyl ammonium pyrophosphate | HCID 21910867 | — |
반응 단계
Tetrasodium diphosphate decahydrate (2.23 g, 5 mmol) was dissolved in water (50 mL), the solution was applied to a column of Dowex 50WX8 (100 mL) in the pyridinium form, and the column was washed with 300 mL water-methanol (1:1). The eluate was directly dropped into a cooled (ice water) and stirred solution of tri-n-butylamine (2.38 mL, 10 mmol) in methanol. The solution was evaporated to dryness and re-evaporated twice with methanol and finally with anhydrous DMF (30 mL) on an oil pump.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US08569259B2 |
| 출처 데이터셋 | uspto-grants-2013_10 |
| ORD ID | ord-ee791794b29348c582575ae51307a739 |
| 출처 메모 | uspto-grants-2013_10 |