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Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
HRID 1046746생성일: 2026년 10월 26일

Azobisisobutyronitrile → Prop-2-enenitrile--ethenylbenzene (1/1)

https://huagongshe.com/reaction/1046746

반응식

참여 물질

역할이름HCID투입량
반응물AzobisisobutyronitrileHCID 6547—
반응물StyreneHCID 7501—
반응물AcrylonitrileHCID 7855—
반응물Tert-dodecanethiolHCID 32793—
생성물Prop-2-enenitrile--ethenylbenzene (1/1)HCID 62696—

반응 조건

온도75 °C

반응 단계

Distilled water in an amount of 115 parts by mass, 1 part by mass of calcium tertiary phosphate, and 0.001 parts by mass of DEMOL P (produced by Kao Corp.) were placed in a reaction vessel and stirred. A mixture of 25 parts by mass of acrylonitrile, 75 parts by mass of styrene, 0.5 parts by mass of t-dodecylmercaptan, 0.17 parts by mass of azobisisobutyronitrile, and 0.003 parts by mass of GAFAC GB-520 (produced by Toho Chemical Industry Co., Ltd.) was added to the reaction vessel to make them a state of suspension, heated up to 75° C., and maintained at the same temperature for 240 minutes to complete the polymerization thereby to obtain acrylonitrile-styrene copolymer resin (x-1). The resin (x-1) thus obtained had a chemical composition of acrylonitrile/styrene=34/66 (mass ratio).

출처 및 근거

DOI10.6084/m9.figshare.5104873.v1
특허 번호US08569403B2
출처 데이터셋uspto-grants-2013_10
ORD IDord-3b34b1eca94b4c33838f7f17e494f098
출처 메모uspto-grants-2013_10