참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Azobisisobutyronitrile | HCID 6547 | — |
| 반응물 | Styrene | HCID 7501 | — |
| 반응물 | Acrylonitrile | HCID 7855 | — |
| 반응물 | Tert-dodecanethiol | HCID 32793 | — |
| 생성물 | Prop-2-enenitrile--ethenylbenzene (1/1) | HCID 62696 | — |
반응 단계
Distilled water in an amount of 115 parts by mass, 1 part by mass of calcium tertiary phosphate, and 0.001 parts by mass of DEMOL P (produced by Kao Corp.) were placed in a reaction vessel and stirred. A mixture of 25 parts by mass of acrylonitrile, 75 parts by mass of styrene, 0.5 parts by mass of t-dodecylmercaptan, 0.17 parts by mass of azobisisobutyronitrile, and 0.003 parts by mass of GAFAC GB-520 (produced by Toho Chemical Industry Co., Ltd.) was added to the reaction vessel to make them a state of suspension, heated up to 75° C., and maintained at the same temperature for 240 minutes to complete the polymerization thereby to obtain acrylonitrile-styrene copolymer resin (x-1). The resin (x-1) thus obtained had a chemical composition of acrylonitrile/styrene=34/66 (mass ratio).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| 특허 번호 | US08569403B2 |
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| 출처 데이터셋 | uspto-grants-2013_10 |
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| ORD ID | ord-3b34b1eca94b4c33838f7f17e494f098 |
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| 출처 메모 | uspto-grants-2013_10 |
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