Diethylamine → (2,2-Diethoxyethyl)diethylamine
반응식
Br[CH2:2][CH:3]([O:7][CH2:8][CH3:9])[O:4][CH2:5][CH3:6].[CH2:10]([NH:12][CH2:13][CH3:14])[CH3:11]>CC(C)=O>[CH2:5]([O:4][CH:3]([O:7][CH2:8][CH3:9])[CH2:2][N:12]([CH2:13][CH3:14])[CH2:10][CH3:11])[CH3:6]참가 물질
4
실험 절차
2-bromo-1,1-diethoxyethane (10 g, 0.051 mol), diethylamine (11 g, 0.15 mol) and KI (8.5 g, 0.051 mol) were added in 100 mL acetone, and stirred for overnight at 40 degree. The resulting solution was filtered, concentrated and purified with silica gel column to give 2,2-diethoxy-N,N-diethylethanamine as brown oil 2.0 g (20.8% yield).
후처리
- filtrationThe resulting solution was filtered
- concentrationconcentrated
- custompurified with silica gel column
출처 및 근거
- ORD 기록
- ord-1d05ce371e2c4dfb971a0a1523dbdd3f
- 출처 데이터셋
- uspto-grants-2016_07
- 특허 번호
- US09388170B2
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