참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Iodine | HCID 807 | — |
| 반응물 | Zinc | HCID 23994 | — |
| 반응물 | Ethyl Nonanoate | HCID 31251 | — |
| 반응물 | Disodium acetylide | HCID 560317 | — |
| 용매 | Dimethylacetamide | HCID 31374 | — |
| 생성물 | HCID 178471365 | HCID 178471365 | — |
반응 단계
In a dry reaction tube under nitrogen were charged zinc dust (3.70 g, 56.6 mmol), iodine (479 mg, 1.89 mmol) and dry DMA (20 mL). The mixture was stirred at room temperature until the color of iodine disappeared. Ethyl 9-bromononanoate was added, and the mixture was stirred at 80° C. for 4 hours and then at room temperature overnight. (Completion of the zinc insertion reaction was checked by GCMS analysis of the hydrolyzed reaction mixture.) The reaction mixture was used without further treatment in the subsequent step. GCMS m/z 186 [M]+ (ethyl nonanoate).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US09393315B2 |
|---|
| 출처 데이터셋 | uspto-grants-2016_07 |
|---|
| ORD ID | ord-0ef785149a124889a3ddb5d4f53c3659 |
|---|
| 출처 메모 | uspto-grants-2016_07 |
|---|
