Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
(4-Chlorophenyl)(phenyl)methanamine → (4-Chlorophenyl)(phenyl)methanamine, (S)-
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | (4-Chlorophenyl)(phenyl)methanamine | HCID 409810 | — |
| 반응물 | D-Tartaric acid | HCID 439655 | — |
| 생성물 | (4-Chlorophenyl)(phenyl)methanamine, (S)- | HCID 736032 | — |
반응 단계
The racemic 4-chlorobenzhydrylamine was treated with D-tartaric acid, and then sequentially recrystallized ten times from water (as described by Clemo, et al., J. Chem. Soc., (1939), 1958-1960) to provide (S)-4-chlorobenzhydrylamine of high optical purity (ee>98%, according to chiral HPLC).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US09399032B2 |
| 출처 데이터셋 | uspto-grants-2016_07 |
| ORD ID | ord-5c7d83a10736459f804e1b03d1c4e82d |
| 출처 메모 | uspto-grants-2016_07 |