(2E)-3-(furan-3-yl)prop-2-enoic acid → 3-(Oxolan-3-yl)propanoic acid

HRID 1058746노트

반응식

HRID 1058746 반응식
[O:1]1[CH:5]=[CH:4][C:3](/[CH:6]=[CH:7]/[C:8]([OH:10])=[O:9])=[CH:2]1.[H][H]>[Pd]>[O:1]1[CH2:5][CH2:4][CH:3]([CH2:6][CH2:7][C:8]([OH:10])=[O:9])[CH2:2]1

참가 물질

4

반응물 2

HCID 643403(2E)-3-(furan-3-yl)prop-2-enoic acidHCID 178418361HCID 178418361, 화합물

생성물 1

HCID 2840903-(Oxolan-3-yl)propanoic acid

시약·촉매·용매 1

HCID 23938Palladium촉매

실험 절차

To a solution of trans-3-furanacrylic acid (10 g, 72.4 mmol) in industrial methylated spirits (50 mL) was added 10% palladium on carbon (1.0 g) at room temperature. The reaction vessel was charged with hydrogen gas to a pressure of 345 kPa and stirred at room temperature for 16 hours. The catalyst was removed by filtration and the filtrate was concentrated in vacuo to give the title compound as a colourless oil.

후처리

  1. customThe catalyst was removed by filtration
  2. concentrationthe filtrate was concentrated in vacuo

출처 및 근거

ORD 기록
ord-6c863cb2aea242c3932cbfa3c441acd2
출처 데이터셋
uspto-grants-2003_02
특허 번호
US06518282B1

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