Sodium Iodide → Cyclododeca-3,7-dien-1-one

HRID 1059265노트

반응식

[O:1]1[CH:3]2[CH2:4][CH2:5][CH:6]=[CH:7][CH2:8][CH2:9][CH:10]=[CH:11][CH2:12][CH2:13][CH:2]12.[I-].[Na+]>>[C:2]1(=[O:1])[CH2:13][CH2:12][CH2:11][CH2:10][CH:9]=[CH:8][CH2:7][CH2:6][CH:5]=[CH:4][CH2:3]1

참가 물질

반응물 2

HCID 5238Sodium Iodide

HCID 791351,2-Epoxycyclododeca-5,9-diene

생성물 1

HCID 69032822Cyclododeca-3,7-dien-1-one수율 98.7%

실험 절차

Also, German Patent No. 3,601,380 discloses that, by isomerization of 1,2-epoxy-5,9-cyclododecadiene in the presence of a catalyst consisting of sodium iodide in a reaction medium consisting of a polyethylene glycol (NaI: 3 wt %, 195° C., 9 hours), cyclododeca-3,7-diene-1-one is produced with a yield of 98.7%.

출처 및 근거

ORD 기록: ord-7be86b7c9730405cb852837ed5bd084b
출처 데이터셋: uspto-grants-2003_02
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US06518461B2

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