Hydroxylamine → 5-Diethylphosphono-2-furaldehyde oxime

HRID 1063599

반응식

HRID 1063599 반응식
[CH2:1]([O:3][P:4]([C:9]1[O:13][C:12]([CH:14]=O)=[CH:11][CH:10]=1)([O:6][CH2:7][CH3:8])=[O:5])[CH3:2].[NH2:16][OH:17].C([O-])(=O)C.[Na+]>C(O)C>[CH2:1]([O:3][P:4]([C:9]1[O:13][C:12]([CH:14]=[N:16][OH:17])=[CH:11][CH:10]=1)([O:6][CH2:7][CH3:8])=[O:5])[CH3:2]

참가 물질

5

반응물 3

HCID 787HydroxylamineHCID 517045Sodium AcetateHCID 46784019Diethyl (5-formylfuran-2-yl)phosphonate

생성물 1

HCID 865864265-Diethylphosphono-2-furaldehyde oxime

시약·촉매·용매 1

HCID 702Ethanol용매

실험 절차

A solution of 5-diethylphosphono-2-furaldehyde (1 mmole) in ethanol was treated with hydroxylamine (1.1 mmole) and sodium acetate (2.2 mmole) at 25° C. for 12 h. Extraction and chromatography gave 5-diethylphosphono-2-furaldehyde oxime.

후처리

  1. extractionExtraction and chromatography

출처 및 근거

ORD 기록
ord-5878d65bc0a0425083231294af4e990c
출처 데이터셋
uspto-grants-2005_11
특허 번호
US06965033B2

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