Methyl fluorosulfate → HCID 12889026, 화합물

반응식

[Br:1][C:2]1[S:6][N:5]=[C:4]([Br:7])[C:3]=1[Br:8].[F:9][S:10]([O:13][CH3:14])(=[O:12])=[O:11]>>[F:9][S:10]([O-:13])(=[O:12])=[O:11].[CH3:14][N+:5]1[S:6][C:2]([Br:1])=[C:3]([Br:8])[C:4]=1[Br:7]

참가 물질

반응물 2

HCID 9870Methyl fluorosulfate

HCID 5150867Isothiazole, tribromo-

생성물 1

HCID 12889026HCID 12889026, 화합물수율 88%

실험 절차

Tribromoisothiazole (2.2 g, 0.007 mol) and 2.2 ml of methyl fluorosulfonate were heated at 65° for 10 min. under a nitrogen atmosphere. The resulting solid was washed with ether and benzene to yield 2.7 g (88%) of 2-methyl-3,4,5-tribromoisothiazolium fluorosulfonate, mp 121-129. Spectral data (NMR and IR) were consistent with the assigned structure.

후처리

washThe resulting solid was washed with ether and benzene

출처 및 근거

ORD 기록: ord-4d8a6fc900ce4442a923b486ea40717a
출처 데이터셋: uspto-grants-1982_05
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US04328347

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