Water → N-acetyl-2-benzylsulfinylacetamide

HRID 1065292노트

반응식

HRID 1065292 반응식
[C:1]([NH:4][C:5](=[O:15])[CH2:6][S:7][CH2:8][C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1)(=[O:3])[CH3:2].[OH2:16]>>[C:1]([NH:4][C:5](=[O:15])[CH2:6][S:7]([CH2:8][C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1)=[O:16])(=[O:3])[CH3:2]

참가 물질

3

반응물 2

HCID 962WaterHCID 12837900HCID 12837900, 화합물

생성물 1

HCID 20540297N-acetyl-2-benzylsulfinylacetamide

실험 절차

To a solution of 0.011 mole of NaIO4 in 25 ml. of water which has been cooled to 5° C. is added 0.01 mole of N-acetyl-2-(benzylthio) acetamide. The reaction mixture is allowed to warm to room temperature and then stirred overnight and concentrated to dryness. Chromatography of the residue on 200 g. of silica gel eluting with ethyl acetate in hexane (25-75%) gives N-acetyl-2-benzylsulfinylacetamide.

후처리

  1. concentrationconcentrated to dryness

출처 및 근거

ORD 기록
ord-bb12e9544b884a5a999e9e38ff883004
출처 데이터셋
uspto-grants-1982_05
특허 번호
US04329363

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