Water → HCID 14848514, 화합물

HRID 1073365노트

반응식

HRID 1073365 반응식
[C:1]([C:5]([Br:8])(Br)[Br:6])([F:4])([F:3])[F:2].[Cl:9][C:10]1[CH:17]=[CH:16][CH:15]=[CH:14][C:11]=1[CH:12]=[O:13].O>CN(C=O)C.[Zn]>[Br:6][C:5]([Br:8])([C:1]([F:4])([F:3])[F:2])[CH:12]([C:11]1[CH:14]=[CH:15][CH:16]=[CH:17][C:10]=1[Cl:9])[OH:13]

참가 물질

6

반응물 3

HCID 962WaterHCID 69962-ChlorobenzaldehydeHCID 677181,1,1-Tribromo-2,2,2-trifluoroethane

생성물 1

HCID 14848514HCID 14848514, 화합물

시약·촉매·용매 2

HCID 23994Zinc촉매HCID 6228Dimethylformamide용매

실험 절차

83.5 g of CF3CBr3 in anhydrous DMF and 28 g of 2-chlorobenzaldehyde were reacted under a nitrogen atmosphere. The mixture was brought to 5° C. and zinc in powder (g.16.0) was added to it slowly. Then the mixture was let reach the room temperature and kept under stirring for 6 hours. The mixture was poured into water and extracted three times with ethyl ether.

후처리

  1. customwas brought to 5° C.
  2. customthe room temperature
  3. extractionextracted three times with ethyl ether

출처 및 근거

ORD 기록
ord-7416b4d1f8264ab08ce0b1c19e42e610
출처 데이터셋
uspto-grants-1990_11
특허 번호
US04968847

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