Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Ethyl Thioglycolate → Ethyl (3-phenoxybenzylthio)acetate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Ethyl Thioglycolate | HCID 12185 | — |
| 반응물 | 1-(Chloromethyl)-4-phenoxybenzene | HCID 520994 | — |
| 반응물 | Sodium ethoxide | HCID 2723922 | — |
| 반응물 | Ethyl (4-methylbenzylthio)acetate | HCID 4107274 | — |
| 용매 | Ethanol | HCID 702 | — |
| 생성물 | Ethyl (3-phenoxybenzylthio)acetate | HCID 53984256 | — |
반응 단계
The procedure is as in Example 29 for the preparation of ethyl (4-methylbenzylthio)acetate, starting with 1-chloromethyl-4-phenoxybenzene (21.5 g), a 2M ethanolic solution of sodium ethylate (50 cc) and ethyl 2-mercaptoacetate (12.2 g) in ethanol (200 cc). Ethyl (3-phenoxybenzylthio)acetate (28.8 g) is thereby obtained, and is used in the crude state in the subsequent syntheses.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04971979 |
| 출처 데이터셋 | uspto-grants-1990_11 |
| ORD ID | ord-31facc416b20404fa2052b44a83341a5 |
| 출처 메모 | uspto-grants-1990_11 |