HCID 9795017, 화합물 → Dibenzo[b,f]thiepin

반응식

[CH:1]1[C:11]2[CH2:10][CH2:9][C:8]3[CH:12]=[CH:13][CH:14]=[CH:15][C:7]=3[S:6][C:5]=2[CH:4]=[C:3](C(O)=O)[CH:2]=1.C1C2C=CC3C=CC=CC=3SC=2C=C(C(O)=O)C=1>>[CH:1]1[C:11]2[CH:10]=[CH:9][C:8]3[CH:12]=[CH:13][CH:14]=[CH:15][C:7]=3[S:6][C:5]=2[CH:4]=[CH:3][CH:2]=1

참가 물질

반응물 2

HCID 9795017HCID 9795017, 화합물

HCID 13151858HCID 13151858, 화합물

생성물 1

HCID 136074Dibenzo[b,f]thiepin

실험 절차

In a similar manner, substituting 10,11-dihydrodibenzo[b,f]thiepin-3-carboxylic acid or dibenzo[b,f]thiepin-3-carboxylic acid for the carboxylic acid starting material employed in Step 1, there is obtained the corresponding 10,11-dihydrobibenzo[b,f]thiepin-3-(4-hydroxy-Δ3 -pyrrolin-3-yl-2,5-dione) or dibenzo[b,f]thiepin-3-(4-hydroxy-Δ3 -pyrrolin-3-yl-2,5-dione).

출처 및 근거

ORD 기록: ord-cc6fe668da2741a8a7ae1382fbb0105d
출처 데이터셋: uspto-grants-1983_07
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US04394515

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