Cyclohexanesulfenyl chloride → HCID 11332618, 화합물

반응식

C1(SCl)C=CC=CC=1.[CH2:9]([S:19][Cl:20])[CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15]CCC.ClC(SCl)=CCl.C1C2C(=CC=CC=2)C=CC=1SCl.C1(SCl)CCCCC1>>[C:10]1([CH2:9][S:19][Cl:20])[CH:11]=[CH:12][CH:13]=[CH:14][CH:15]=1

참가 물질

반응물 5

HCID 87312Cyclohexanesulfenyl chloride

HCID 11008040Benzenesulfenyl chloride

HCID 124820622-Naphthalenesulfenyl chloride

HCID 21983338HCID 21983338, 화합물

HCID 54122024HCID 54122024, 화합물

생성물 1

HCID 11332618HCID 11332618, 화합물

실험 절차

Similarly, repeating the above procedure but replacing the benzenesulfenyl chloride as used therein with an equal molar proportion of each of decanesulfenyl chloride (prepared by chlorination of decanedisulfide according to the method of Douglass, supra.), 1,2-dichlorovinylsulfenyl chloride, 2-naphthalenesulfenyl chloride, cyclohexanesulfenyl chloride (prepared by chlorination of cyclohexanedisulfide, according to the method of Douglass, supra.) and α-toluenesulfenyl chloride, respectively, there is obtained: