Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Acetic Acid → Prenyl acetate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Acetic Acid | HCID 176 | — |
| 반응물 | Boric Acid | HCID 7628 | — |
| 반응물 | 2-Methyl-3-buten-2-ol | HCID 8257 | — |
| 반응물 | Sodium Carbonate | HCID 10340 | — |
| 용매 | Water | HCID 962 | — |
| 생성물 | Prenyl acetate | HCID 14489 | — |
반응 단계
A mixture of 3-methyl-3-hydroxybut-1-ene (32 g.), acetic acid (150 ml.) and boric acid (30 g.) was stirred at 105° for 4 hours. The cooled reaction mixture was diluted with water, neutralised with solid sodium carbonate and extracted with ether (3 × 50 ml.) The combined ethereal extracts were brine washed, dried and the solvent removed giving a pale yellow oil (30 g.) Distillation gave 3,3-dimethylallyl acetate as a colourless oil (22 g.) b.p. 44°-45°/14 mm Hg.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US03959278 |
| 출처 데이터셋 | uspto-grants-1976_05 |
| ORD ID | ord-5a6478e8ddca4c1e869c8ab19303fc96 |
| 출처 메모 | uspto-grants-1976_05 |