Benzenesulfenyl chloride, 2,4-dinitro- → Sulfide, bis(2,4-dinitrophenyl)

HRID 1077067

반응식

HRID 1077067 반응식
[N+:1]([C:4]1[CH:9]=[C:8]([N+:10]([O-:12])=[O:11])[CH:7]=[CH:6][C:5]=1[S:13]Cl)([O-:3])=[O:2]>C(O)(=O)C>[N+:1]([C:4]1[CH:9]=[C:8]([N+:10]([O-:12])=[O:11])[CH:7]=[CH:6][C:5]=1[S:13][C:5]1[CH:6]=[CH:7][C:8]([N+:10]([O-:12])=[O:11])=[CH:9][C:4]=1[N+:1]([O-:3])=[O:2])([O-:3])=[O:2]

참가 물질

3

반응물 1

HCID 68251Benzenesulfenyl chloride, 2,4-dinitro-

생성물 1

HCID 95960Sulfide, bis(2,4-dinitrophenyl)

시약·촉매·용매 1

HCID 176Acetic Acid용매

실험 절차

To 1.38 g. of 3-butenyltributyltin was added 0.936 g. of 2,4-dinitrobenzene sulfenyl chloride in 20 ml. glacial acetic acid at steam bath temperature. The reaction mixture was warned on the steam bath for 20 minutes, poured into ice water and filtered. The mixture was extracted with pentane, dried and recrystallized from ethanol to yield cyclopropylcarbinyl 2,4-dinitrophenyl sulfide; m.p. 80°-81°C. Analysis for C and H confirmed the composition of the reaction product.

후처리

  1. filtrationfiltered
  2. extractionThe mixture was extracted with pentane
  3. customdried
  4. customrecrystallized from ethanol

출처 및 근거

ORD 기록
ord-01e11c12a58f4022a2327f1f61a060a3
출처 데이터셋
uspto-grants-1976_05
특허 번호
US03959324

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