2-Butyl-2-ethyl-1,3-propanediol → 5-Butyl-5-ethyl-2-(4-nitrobenzyl)-1,3,2-dioxaphosphorinan-2-oxide

HRID 1079314

반응식

HRID 1079314 반응식
[N+:1]([C:4]1[CH:14]=[CH:13][C:7]([CH2:8][P:9](=[O:12])([OH:11])[OH:10])=[CH:6][CH:5]=1)([O-:3])=[O:2].[CH2:15]([C:19]([CH2:24][CH3:25])([CH2:22]O)[CH2:20]O)[CH2:16][CH2:17][CH3:18]>>[CH2:15]([C:19]1([CH2:24][CH3:25])[CH2:22][O:11][P:9](=[O:10])([CH2:8][C:7]2[CH:13]=[CH:14][C:4]([N+:1]([O-:3])=[O:2])=[CH:5][CH:6]=2)[O:12][CH2:20]1)[CH2:16][CH2:17][CH3:18]

참가 물질

3

반응물 2

HCID 610382-Butyl-2-ethyl-1,3-propanediolHCID 5180708(4-Nitro-benzyl)-phosphonic acid

생성물 1

HCID 189280705-Butyl-5-ethyl-2-(4-nitrobenzyl)-1,3,2-dioxaphosphorinan-2-oxide

실험 절차

With 4-nitrobenzylphosphonic acid and 2-butyl-2-ethyl-1,3-propanediol, the same procedure as in Reference Example 11 was followed, to yield 5-butyl-5-ethyl-2-(4-nitrobenzyl)- 1,3,2-dioxaphosphorinane-2-oxide, which was then recrystallized from ethanol-hexane to yield colorless prisms having a melting point of 111° to 112° C.

출처 및 근거

ORD 기록
ord-b8c1778d87bf4c00bb11985aa266a0e2
출처 데이터셋
uspto-grants-1996_12
특허 번호
US05580863

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