Acetic acid, (3-methylphenoxy)- → N-(2-Nitroxyethyl)-3-methylphenoxyacetamide

HRID 1079448노트

반응식

HRID 1079448 반응식
[CH3:1][C:2]1[CH:3]=[C:4]([CH:10]=[CH:11][CH:12]=1)[O:5][CH2:6][C:7]([OH:9])=O.[N+]([O-])(O)=O.[O:17]([CH2:21][CH2:22][NH2:23])[N+:18]([O-:20])=[O:19]>CCCCCC>[O:17]([CH2:21][CH2:22][NH:23][C:7](=[O:9])[CH2:6][O:5][C:4]1[CH:10]=[CH:11][CH:12]=[C:2]([CH3:1])[CH:3]=1)[N+:18]([O-:20])=[O:19]

참가 물질

4

반응물 2

HCID 74235Acetic acid, (3-methylphenoxy)-HCID 78397Ethanol, 2-amino-, 1-nitrate, nitrate (1:1)

생성물 1

HCID 15839958N-(2-Nitroxyethyl)-3-methylphenoxyacetamide수율 55.4%

시약·촉매·용매 1

HCID 8058Hexane용매

실험 절차

Following a similar treatment to that in Example 2 and using 0.71 g of 3-methylphenoxyacetic acid and 0.6 g of 2-nitroxyethylamine nitrate, 0.50 g of the title compound was obtained as colorless powdery crystals (solvent for recrystallization; hexane).

출처 및 근거

ORD 기록
ord-393c2e144f7b4afcab952383460f260a
출처 데이터셋
uspto-grants-1996_12
특허 번호
US05580893

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