Acetone → Ruthenium bis bipyridyl dichloride

HRID 1081231노트

반응식

HRID 1081231 반응식
O.O.O.[Ru:4](Cl)(Cl)[Cl:5].[N:8]1[CH:13]=[CH:12][CH:11]=[CH:10][C:9]=1[C:14]1[CH:19]=[CH:18][CH:17]=[CH:16][N:15]=1.[Cl-:20].[Li+].CC(C)=O>CN(C)C=O>[Cl-:5].[Cl-:20].[N:8]1[CH:13]=[CH:12][CH:11]=[CH:10][C:9]=1[C:14]1[CH:19]=[CH:18][CH:17]=[CH:16][N:15]=1.[N:8]1[CH:13]=[CH:12][CH:11]=[CH:10][C:9]=1[C:14]1[CH:19]=[CH:18][CH:17]=[CH:16][N:15]=1.[Ru+2:4]

참가 물질

6

반응물 4

HCID 180AcetoneHCID 14742,2'-BipyridineHCID 433294Lithium ChlorideHCID 12090026Ruthenium chloride trihydrate

생성물 1

HCID 9805343Ruthenium bis bipyridyl dichloride

시약·촉매·용매 1

HCID 6228Dimethylformamide용매

반응 조건

온도
15 °C

실험 절차

A mixture of ruthenium trichloride trihydrate (2.5 g), 2,2' bipyridyl (3.0 g) and lithium chloride (5.0 g) was placed in 50 ml of DMF under nitrogen. This mixtrue was stirred and refluxed for 7 hours. The resulting purple/black solution was allowed to cool slowly to about 15° C. with continued stirring. 250 ml of acetone was then added and the flask stoppered under nigrogen. This solution was left at 0° C. for 24 hours. A black microcrystalline solid was recovered by filtration which was washed with water three times and diethyl ether three times.

후처리

  1. temperaturerefluxed for 7 hours
  2. filtrationA black microcrystalline solid was recovered by filtration which
  3. washwas washed with water three times and diethyl ether three times

출처 및 근거

ORD 기록
ord-0b209bab7d8b4bb3aec4d4f3238c613a
출처 데이터셋
uspto-grants-1996_12
특허 번호
US05585279

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