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llms.txt · MCP 가이드개인정보처리방침 · 이용약관 · 지원v1.8.0
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Water → HCID 86747077, 화합물

HRID 1081975
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HRID 1081975 반응식
[C:1]1([Li])[C:13]2[CH2:12][C:11]3[C:6](=[CH:7][CH:8]=[CH:9][CH:10]=3)[C:5]=2[CH:4]=[CH:3][CH:2]=1.[CH3:15][C:16]([C:22]1[CH:27]=[CH:26][CH:25]=[CH:24][CH:23]=1)=[C:17]1[CH:21]=[CH:20][CH:19]=[CH:18]1.O>C1COCC1.[Cl-].[Cl-].C1(C(=[Zr+2](C2C3C=CC=CC=3C3C2=CC=CC=3)C2C=CC=C2)C)C=CC=CC=1>[CH:17]1([C:16]2[CH:15]=[CH:25][CH:26]=[CH:27][C:22]=2[CH2:23][CH2:24][CH:12]2[C:11]3[CH:10]=[CH:9][CH:8]=[CH:7][C:6]=3[C:5]3[C:13]2=[CH:1][CH:2]=[CH:3][CH:4]=3)[CH2:18][CH2:19][CH:20]=[CH:21]1
참가 물질실험 절차후처리출처 및 근거반응 노트

참가 물질

6

반응물 3

HCID 962WaterHCID 5928226-Methyl-6-phenylfulveneHCID 178506660HCID 178506660, 화합물

생성물 1

HCID 86747077HCID 86747077, 화합물수율 84.2%

시약·촉매·용매 2

HCID 178436121HCID 178436121, 화합물촉매HCID 8028Tetrahydrofuran용매
2회

실험 절차

(Phenyl(methyl)methylene)(9-fluorenyl)(cyclopentadienyl)zirconium dichloride ##STR9## A solution of 67.8 mmol of fluorenyllithium of 50 cm3 of THF was added at room temperature to a solution of 11.4 g (67.8 mmol) of 6-methyl-6-phenylfulvene in 40 cm3 of THF. The mixture was stirred at room temperature for 2 hours, and 60 cm3 of water were added. The substance which precipitated was filtered off with suction, washed with diethyl ether and dried in an oil-pump vacuum. 19.1 g (84.2%) of 2,2-cyclopentadienyl(9-fluorenyl)ethylbenzene (correct elemental analyses; 1H-NMR spectrum) were obtained.

후처리

  1. customThe substance which precipitated
  2. filtrationwas filtered off with suction
  3. washwashed with diethyl ether
  4. customdried in an oil-pump vacuum

출처 및 근거

ORD 기록
ord-96e390960f0640c8b94903fb53c8bc82
출처 데이터셋
uspto-grants-1996_12
DOI
10.6084/m9.figshare.5104873.v1
특허 번호
US05587501

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