참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Stannous Chloride | HCID 24479 | — |
| 반응물 | 4-Amino-5,6,7,8-tetrahydronaphthalene-1-carboxylic acid | HCID 22111798 | — |
| 반응물 | Sodium Nitrite | HCID 23668193 | — |
| 용매 | Hydrochloric Acid | HCID 313 | — |
| 용매 | Water | HCID 962 | — |
| 생성물 | 4-Hydrazino-5,6,7,8-tetrahydro-1-naphthalenecarboxylic acid hydrochloride | HCID 70245475 | 73.3% |
반응 단계
A solution of 0.26 g of NaNO2 in 1 ml of water is added to a solution, cooled to -5° C., of 0.73 g of 4-amino-5,6,7,8-tetrahydro-1-naphthalenecarboxylic acid in 10 ml of concentrated HCl. After one and a half hours of stirring at -5° C., a solution of 3.4 g of SnCl2 ·2H2O in 34 ml of concentrated HCl is added at -5° C. The mixture is stirred for 1 hour at RT and filtered, and the product is washed with concentrated HCl and dried under a stream of dry nitrogen to obtain 0.67 g of the expected hydrazine.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US05723483 |
|---|
| 출처 데이터셋 | uspto-grants-1998_03 |
|---|
| ORD ID | ord-7bfae8fa5eb84c9b9f50ce2960b99ca7 |
|---|
| 출처 메모 | uspto-grants-1998_03 |
|---|
