Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
1,3-Dibromo-5,5-dimethylhydantoin → 5-(Bromomethyl)quinoxaline
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 1,3-Dibromo-5,5-dimethylhydantoin | HCID 6479 | — |
| 반응물 | 5-Methylquinoxaline | HCID 61670 | — |
| 반응물 | Perbenzoic acid | HCID 523077 | — |
| 용매 | Carbon Tetrachloride | HCID 5943 | — |
| 생성물 | 5-(Bromomethyl)quinoxaline | HCID 10149129 | 100% |
반응 단계
A mixture of 10 parts of 5-methylquinoxaline, 10 parts of 1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione, 1.7 parts of benzenecarboperoxoic acid and 318 parts of tetrachloromethane was stirred for 16 hours at reflux temperature under 2 lamps of 250 Watt. The reaction mixture was cooled and the organic layer was decanted. The product was filtered off and dried, yielding 15.5 parts (100%) of 5-(bromomethyl)quinoxaline (interm. 1).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05028606 |
| 출처 데이터셋 | uspto-grants-1991_07 |
| ORD ID | ord-920d3c4d604942e0800b3ae7e6412350 |
| 출처 메모 | uspto-grants-1991_07 |