Acetic Acid → Hydroxyethyl-2,6-dinitro-p-anisidine

HRID 1086385노트

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HRID 1086385 반응식
CO[C:3]1[C:10]([N+:11]([O-:13])=[O:12])=[CH:9][C:6]([O:7][CH3:8])=[CH:5][C:4]=1[N+:14]([O-:16])=[O:15].C(O)(=O)C.[CH2:21]([CH2:23][NH2:24])[OH:22]>>[N+:11]([C:10]1[CH:9]=[C:6]([O:7][CH3:8])[CH:5]=[C:4]([N+:14]([O-:16])=[O:15])[C:3]=1[NH:24][CH2:23][CH2:21][OH:22])([O-:13])=[O:12]

참가 물질

4

반응물 3

HCID 176Acetic AcidHCID 700EthanolamineHCID 12249848Benzene, 2,5-dimethoxy-1,3-dinitro-

생성물 1

HCID 17758312Hydroxyethyl-2,6-dinitro-p-anisidine

실험 절차

1 g of 2,6-dinitro-hydroquinone dimethyl ether (B. Relchert and W. Turkewitsch, Arch. der Pharmazie 276, 397, 406 (1938)) was stirred in 15 ml of ethanol amine for one hour at room temperature, whereupon the mixture was poured on ice and neutralized with acetic acid. The precipitated red crystals were filtered with suction. 0.9 g (78 percent of the theoretical yield) of the product was obtained; it has a melting point of 104° C.

후처리

  1. filtrationThe precipitated red crystals were filtered with suction
  2. custom0.9 g (78 percent of the theoretical yield) of the product
  3. customwas obtained

출처 및 근거

ORD 기록
ord-813a34dccc9449089791eea5eb0a419a
출처 데이터셋
uspto-grants-1991_07
특허 번호
US05030241

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