Phosphorus pentachloride → 3-(2,4-Difluorophenylthio)-4-nitrobenzoyl chloride
반응식
[F:1][C:2]1[CH:7]=[C:6]([F:8])[CH:5]=[CH:4][C:3]=1[S:9][C:10]1[CH:11]=[C:12]([CH:16]=[CH:17][C:18]=1[N+:19]([O-:21])=[O:20])[C:13](O)=[O:14].P(Cl)(Cl)(Cl)(Cl)[Cl:23]>C1C=CC=CC=1>[F:1][C:2]1[CH:7]=[C:6]([F:8])[CH:5]=[CH:4][C:3]=1[S:9][C:10]1[CH:11]=[C:12]([CH:16]=[CH:17][C:18]=1[N+:19]([O-:21])=[O:20])[C:13]([Cl:23])=[O:14]참가 물질
4
실험 절차
A mixture of 3-(2,4-difluorophenylthio)-4-nitrobenzoic acid (1 g) and phosphorus pentachloride (0.7 g) in benzene (10 ml) was stirred at room temperature for 30 minutes. The mixture was concentrated under reduced pressure to give a powder of 3-(2,4-difluorophenylthio)-4-nitrobenzoyl chloride (1.2 g).
후처리
- concentrationThe mixture was concentrated under reduced pressure
출처 및 근거
- ORD 기록
- ord-7cdfacbfe9bc4c31985c6b2585c95e8e
- 출처 데이터셋
- uspto-grants-1991_07
- 특허 번호
- US05034417
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