1-Methyl-1H-pyrrole-2-carbaldehyde → 4-[3-(2-Pyridyl)-2-propenoyl)benzaldehyde Diethyl Acetal

HRID 1087417

반응식

HRID 1087417 반응식
CN1C=CC=C1C=O.C(N1C=CN=C1C=O)C1C=CC=CC=1.[CH2:23]([O:25][CH:26]([O:43][CH2:44][CH3:45])[C:27]1[CH:32]=[CH:31][C:30]([C:33](=[O:42])[CH:34]=[CH:35][C:36]2[N:37]([CH3:41])[CH:38]=[CH:39][CH:40]=2)=[CH:29][CH:28]=1)[CH3:24].C(N1C=CN=C1C=CC(C1C=CC(C=O)=CC=1)=O)C1C=CC=CC=1>>[CH2:23]([O:25][CH:26]([O:43][CH2:44][CH3:45])[C:27]1[CH:32]=[CH:31][C:30]([C:33](=[O:42])[CH:34]=[CH:35][C:36]2[CH:40]=[CH:39][CH:38]=[CH:41][N:37]=2)=[CH:29][CH:28]=1)[CH3:24]

참가 물질

5

반응물 4

HCID 145041-Methyl-1H-pyrrole-2-carbaldehydeHCID 1390821-benzyl-1H-imidazole-2-carbaldehydeHCID 538530924-[3-(1-Benzyl-2-imidazolyl)-2-propenoyl)benzaldehydeHCID 571359684-[3-(1-Methyl-2-pyrrolyl)-2-propenoyl)benzaldehyde diethyl acetal

생성물 1

HCID 572900004-[3-(2-Pyridyl)-2-propenoyl)benzaldehyde Diethyl Acetal

실험 절차

By the same method N-methylpyrrole-2-carbaldehyde and 1-benzyl imidazole-2-carbaldehyde are converted to 4-[3-(1-methyl-2-pyrrolyl)-2-propenoyl)benzaldehyde diethyl acetal and 4-[3-(1-benzyl-2-imidazolyl)-2-propenoyl)benzaldehyde.

출처 및 근거

ORD 기록
ord-16592a4a333b4014b452415483cbe612
출처 데이터셋
uspto-grants-1991_07
특허 번호
US05036079

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