m-Chloroperbenzoic acid → 4-(4,5-Epoxypentoxy)-4'-nitrobiphenyl

HRID 1088427

반응식

HRID 1088427 반응식
[CH2:1]([O:6][C:7]1[CH:12]=[CH:11][C:10]([C:13]2[CH:18]=[CH:17][C:16]([N+:19]([O-:21])=[O:20])=[CH:15][CH:14]=2)=[CH:9][CH:8]=1)[CH2:2][CH2:3][CH:4]=[CH2:5].ClC1C=CC=C(C(OO)=[O:30])C=1>C(Cl)Cl>[O:30]1[CH2:5][CH:4]1[CH2:3][CH2:2][CH2:1][O:6][C:7]1[CH:12]=[CH:11][C:10]([C:13]2[CH:14]=[CH:15][C:16]([N+:19]([O-:21])=[O:20])=[CH:17][CH:18]=2)=[CH:9][CH:8]=1

참가 물질

4

반응물 2

HCID 70297m-Chloroperbenzoic acidHCID 199012844-(4-Pentenoxy)-4'-nitrobiphenyl

생성물 1

HCID 221630194-(4,5-Epoxypentoxy)-4'-nitrobiphenyl

시약·촉매·용매 1

HCID 6344Dichloromethane용매

반응 조건

온도
0 °C

실험 절차

To 250 ml of methylene chloride is added 28.3 g of 4-(4-penteneoxy)-4'-nitrobiphenyl. The solution is cooled to 0° C., and 18 g of meta-chloroperbenzoic acid is added slowly. The mixture is stirred at 0° C. for 24 hours, and allowed to warm to room temperature.

후처리

  1. temperatureto warm to room temperature

출처 및 근거

ORD 기록
ord-0ee21c4eba164910add49f0fd8393a22
출처 데이터셋
uspto-grants-1990_10
특허 번호
US04962160

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