Benzene → p-acetyl-N-(alpha-methyl benzylidene) aniline

HRID 1088518

반응식

HRID 1088518 반응식
C([C:4]1[CH:9]=[CH:8][C:7]([C:10](=[O:12])[CH3:11])=[CH:6][CH:5]=1)(=O)C.[NH2:13][C:14]1C=CC=C[CH:15]=1.[CH:20]1[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=1>O>[C:10]([C:7]1[CH:6]=[CH:5][C:4]([N:13]=[C:14]([CH3:15])[C:20]2[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=2)=[CH:9][CH:8]=1)(=[O:12])[CH3:11]

참가 물질

5

반응물 3

HCID 241BenzeneHCID 6115AnilineHCID 138881,4-Diacetylbenzene

생성물 1

HCID 54464667p-acetyl-N-(alpha-methyl benzylidene) aniline

시약·촉매·용매 1

HCID 962Water용매

실험 절차

A solution of p-diacetylbenzene (50 g), aniline (80 g) and benzene (120 ml) was refluxed in the presence of molecular sieve (10 g) with continuous removal of water. The crude product was crystallized from ethanol to give p-acetyl-N-(α-methyl benzylidene) aniline (XXIII). XXIII had a melting point of 205° C.

후처리

  1. customThe crude product was crystallized from ethanol

출처 및 근거

ORD 기록
ord-d201f1638125472290ebfcaa4a3cefeb
출처 데이터셋
uspto-grants-1990_10
특허 번호
US04962234

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