Benzene → N-(1,2,3,4-tetrahydronaphthylidene) aniline

HRID 1088521노트

반응식

HRID 1088521 반응식
C1CC(=O)C2C(=CC=CC=2)C1.[CH2:12]([NH:24][C:25]1[CH:30]=[CH:29][CH:28]=[CH:27][CH:26]=1)[CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21]CC.C1C=CC=CC=1>O>[C:12]1(=[N:24][C:25]2[CH:26]=[CH:27][CH:28]=[CH:29][CH:30]=2)[C:13]2[C:18](=[CH:17][CH:16]=[CH:15][CH:14]=2)[CH2:19][CH2:20][CH2:21]1

참가 물질

5

반응물 3

HCID 241BenzeneHCID 107241-TetraloneHCID 76362N-Dodecylaniline

생성물 1

HCID 11183633N-(1,2,3,4-tetrahydronaphthylidene) aniline

시약·촉매·용매 1

HCID 962Water용매

실험 절차

A solution of α-tetralone (50 ml), dodecyl aniline (80 g) and benzene (150 ml) was refluxed in the presence of molecular sieve (100 g) with continuous removal of water. The crude product was crystallized from ethanol to give N-(1,2,3,4-tetrahydronaphthylidene) aniline (XXVI). XXVI had a melting point of 53° C.

후처리

  1. customThe crude product was crystallized from ethanol

출처 및 근거

ORD 기록
ord-e154c3d869d346daa6428db55c1f5c1a
출처 데이터셋
uspto-grants-1990_10
특허 번호
US04962234

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