1,1-Dichlorosilacyclobutane → 1,1-Diacetoxysilacyclobutane

HRID 1089317

반응식

HRID 1089317 반응식
C[Si]([CH2:5][C:6]([O-:8])=[O:7])(C)C.Cl[Si:10]1(Cl)[CH2:13][CH2:12][CH2:11]1>>[C:6]([O:8][Si:10]1([O:8][C:6](=[O:7])[CH3:5])[CH2:13][CH2:12][CH2:11]1)(=[O:7])[CH3:5]

참가 물질

3

반응물 2

HCID 753731,1-DichlorosilacyclobutaneHCID 225582202-Trimethylsilylacetate

생성물 1

HCID 150659191,1-Diacetoxysilacyclobutane

반응 조건

온도
25 °C

실험 절차

To 30.0 g trimethylsilylacetate was added 16.0 g 1,1-dichlorosilacyclobutane. The reactants were stirred for one hour at 25 ° C. and fractional distillation performed on the reaction mixture. The title compound was isolated as a clear, colorless fluid. The yield was 14.6 g (81.4%). The structure of the product was confirmed by mass spectroscopy and nuclear magnetic resonance spectroscopy (NMR).

후처리

  1. distillationfractional distillation

출처 및 근거

ORD 기록
ord-f4d327f92e4a4de5b56a0b7b9b71e94e
출처 데이터셋
uspto-grants-1990_10
특허 번호
US04965367

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