3-Phenoxy-1,2-propanediol → Phenoxyacetaldehyde
반응식
I([O-])(=O)(=O)=O.[Na+].[O:7]([CH2:14][CH:15]([OH:18])CO)[C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=1>ClCCl>[O:7]([CH2:14][CH:15]=[O:18])[C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=1참가 물질
4
실험 절차
Sodium periodate (0.65 M in water, 20 mL) was added to a vigorously stirred suspension of silica gel (20 g) in dichloromethane (160 mL), followed by a solution of 3-phenoxy-1,2-propanediol (1.68 g, 10.0 mmol) in dichloromethane (20 mL). After stirring for 10 min the mixture was filtered and the filtrate was concentrated to give the subtitle compound (1.36 g, 100%).
후처리
- filtrationwas filtered
- concentrationthe filtrate was concentrated
출처 및 근거
- ORD 기록
- ord-15b9268a4a2f477988dae515e9076246
- 출처 데이터셋
- uspto-grants-2012_03
- 특허 번호
- US08143290B2
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