Sodium Iodide → HCID 12852738, 화합물

HRID 1105882노트

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HRID 1105882 반응식
Cl[C:2]1[S:6][N:5]([CH2:7][CH2:8][C:9]2[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=2)[C:4](=[O:15])[CH:3]=1.[Na+].[CH2:17]([N:24]([CH2:28][C:29]1[CH:34]=[CH:33][CH:32]=[CH:31][CH:30]=1)[C:25](=[S:27])[S-:26])[C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1.[I-].[Na+]>C(O)C>[CH2:28]([N:24]([CH2:17][C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1)[C:25]([S:27][C:2]1[S:6][N:5]([CH2:7][CH2:8][C:9]2[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=2)[C:4](=[O:15])[CH:3]=1)=[S:26])[C:29]1[CH:30]=[CH:31][CH:32]=[CH:33][CH:34]=1

참가 물질

5

반응물 3

HCID 5238Sodium IodideHCID 4676203Carbamodithioic acid, bis(phenylmethyl)-, sodium saltHCID 13013787HCID 13013787, 화합물

생성물 1

HCID 12852738HCID 12852738, 화합물

시약·촉매·용매 1

HCID 702Ethanol용매

실험 절차

To a solution of 4.8 g. (0.02 mole) of 5-chloro-2-phenethyl-4-isothiazolin-3-one in 35 ml of ethanol was added 5.9 g. (0.02 mole) of N,N-dibenzyldithiocarbamic acid sodium salt followed by 0.15 g. sodium iodide. The mixture was concentrated in vacuo and the residue was treated with 300 ml of boiling hexane under reflux. The hexane solution decanted and cooled to give 0.63 g. of the named product, mp 98°-100°.

후처리

  1. concentrationThe mixture was concentrated in vacuo
  2. additionthe residue was treated with 300 ml of boiling hexane
  3. temperatureunder reflux
  4. customThe hexane solution decanted
  5. temperaturecooled
  6. customto give 0.63 g

출처 및 근거

ORD 기록
ord-478a3cafc896449abcdd376d7e565764
출처 데이터셋
uspto-grants-1982_01
특허 번호
US04310590

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