Metaperiodic acid → (+-)-6-Methoxy-2,6-dimethylheptanal

HRID 1105999노트

반응식

HRID 1105999 반응식
[CH3:1][O:2][C:3]([CH3:14])([CH3:13])[CH2:4][CH2:5][CH2:6][CH:7]([CH3:12])[CH:8]([OH:11])CO.I(O)(=O)(=O)=O.C(=O)(O)[O-].[Na+]>O>[CH3:1][O:2][C:3]([CH3:13])([CH3:14])[CH2:4][CH2:5][CH2:6][CH:7]([CH3:12])[CH:8]=[O:11]

참가 물질

5

반응물 3

HCID 65185Metaperiodic acidHCID 1124901,2-Octanediol, 7-methoxy-3,7-dimethyl-HCID 516892Sodium Bicarbonate

생성물 1

HCID 112491(+-)-6-Methoxy-2,6-dimethylheptanal수율 29.7%

시약·촉매·용매 1

HCID 962Water용매

실험 절차

7-Methoxy-3,7-dimethyl octan-1,2-diol (40 g) was treated with periodic acid in tetrahydrofuren; work up with water followed by diluted sodium bicarbonate wash gave the aldehyde (10 g) with specific rotating α(22/D+13.69.

후처리

  1. washwash

출처 및 근거

ORD 기록
ord-532a102e96824f5697efc2a90829ec12
출처 데이터셋
uspto-grants-1982_01
특허 번호
US04311617

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