Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Fenvalerate → (alphaS)-4-Chloro-alpha-(1-methylethyl)benzeneacetic acid
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Fenvalerate | HCID 3347 | — |
| 촉매 | Platinum oxide (PtO) | HCID 82844 | — |
| 용매 | Ethanol | HCID 702 | — |
| 생성물 | (alphaS)-4-Chloro-alpha-(1-methylethyl)benzeneacetic acid | HCID 854132 | — |
반응 단계
The optical purity of the acid moiety of fenvalerate A was determined as follows: Fenvalerate A was hydrogenated in ethanol using platinum oxide as a catalyst to obtain (S)-2-(4-chlorophenyl)isovaleric acid which was then converted to an acid chloride using thionyl chloride. The acid chloride was converted to the l-menthol ester with l-menthol. The ratio between the two resulting diastereomers was determined by gas chromatography, and the optical purity of the acid moiety was calculated.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04312816 |
| 출처 데이터셋 | uspto-grants-1982_01 |
| ORD ID | ord-89baf99e75394998ae7cfacb63ae062a |
| 출처 메모 | uspto-grants-1982_01 |