Water → 1-Nonyn-4-one

HRID 1106295노트

반응식

HRID 1106295 반응식
[CH:1]#[C:2][CH2:3][CH:4]([OH:10])[CH2:5][CH2:6][CH2:7][CH2:8][CH3:9].CC(C)=O.OS(O)(=O)=O.O=[Cr](=O)=O.CCCCCC.O>CC(C)=O>[CH:1]#[C:2][CH2:3][C:4](=[O:10])[CH2:5][CH2:6][CH2:7][CH2:8][CH3:9]

참가 물질

6

반응물 4

HCID 962WaterHCID 8058HexaneHCID 109863221-Nonyn-4-olHCID 131709961Jones' reagent

생성물 1

HCID 205539671-Nonyn-4-one

시약·촉매·용매 1

HCID 180Acetone용매

실험 절차

A solution of 14 g of 1-nonyn-4-ol in 100 ml of acetone is cooled to 0° and treated dropwise with 70 ml of 2.67 molar Jones reagent with stirring. The reaction mixture is poured into a mixture of hexane and water, the organic layer is separated and washed with water, dried over sodium sulfate, stripped of solvent, and the residue distilled to give the title product.

후처리

  1. customthe organic layer is separated
  2. washwashed with water
  3. dry with materialdried over sodium sulfate
  4. distillationthe residue distilled

출처 및 근거

ORD 기록
ord-fdf6124e36594f11b8fdd3d79d68d91a
출처 데이터셋
uspto-grants-1982_01
특허 번호
US04312994

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