Dimethylformamide diethylacetal → HCID 54176307, 화합물

HRID 1106568노트

반응식

HRID 1106568 반응식
[CH2:1]([O:8][C:9]1[CH:18]=[C:17]2[C:12]([CH2:13][CH2:14][CH2:15][C:16]2=[O:19])=[CH:11][CH:10]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.C(O[CH:23](OCC)[N:24]([CH3:26])[CH3:25])C>>[CH2:1]([O:8][C:9]1[CH:18]=[C:17]2[C:12]([CH2:13][CH2:14][C:15](=[CH:23][N:24]([CH3:26])[CH3:25])[C:16]2=[O:19])=[CH:11][CH:10]=1)[C:2]1[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=1

참가 물질

3

반응물 2

HCID 70913Dimethylformamide diethylacetalHCID 140682207-(Benzyloxy)-3,4-dihydronaphthalen-1(2H)-one

생성물 1

HCID 54176307HCID 54176307, 화합물

실험 절차

7-Benzyloxy-3,4-dihydro-2-dimethylaminomethylene -1(2H)naphthalenone was prepared from 7-benzyloxy-3,4-dihydro-1(2H)naphthalenone (6.0 g, 23.8 mmol) and N,N-dimethylformamide diethylacetal (20 ml, 119.4 mmol) to give the desired compound as a pale yellow solid (4.56 g) m.p. 85-86°. MS(ES+) 308 (MH+, 100%).

출처 및 근거

ORD 기록
ord-4e59482f99724dae83361f1d277098d3
출처 데이터셋
uspto-grants-2000_05
특허 번호
US06057329

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