(3-Amino-4-methylphenoxy) acetonitrile → (3-Amino-5-chloro-4-methylphenyl) acetonitrile

HRID 1106757노트

반응식

HRID 1106757 반응식
[Cl:1][C:2]1[CH:3]=[C:4]([CH2:12][C:13]#[N:14])[CH:5]=[C:6]([N+:9]([O-])=O)[C:7]=1[CH3:8].NC1C=C(C=CC=1C)OCC#N.CC1C=CC(OCC#N)=CC=1[N+]([O-])=O>>[NH2:9][C:6]1[CH:5]=[C:4]([CH2:12][C:13]#[N:14])[CH:3]=[C:2]([Cl:1])[C:7]=1[CH3:8]

참가 물질

4

반응물 3

HCID 18789626(3-Amino-4-methylphenoxy) acetonitrileHCID 18789631(4-Methyl-3-nitrophenoxy) acetonitrileHCID 54125367(3-Chloro-4-methyl-5-nitrophenyl) acetonitrile

생성물 1

HCID 54396229(3-Amino-5-chloro-4-methylphenyl) acetonitrile

실험 절차

(3-Amino-5-chloro-4-methylphenyl) acetonitrile was prepared from (3-chloro-4-methyl-5-nitrophenyl) acetonitrile in a manner similar to that described in Example 2 for the preparation of (3-amino-4-methylphenoxy) acetonitrile from (4-methyl-3-nitrophenoxy) acetonitrile.

출처 및 근거

ORD 기록
ord-522085e023c241be827553fdb1eb84cc
출처 데이터셋
uspto-grants-2000_05
특허 번호
US06057349

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