Propane, 1,1-dichloro-1,3,3,3-tetrafluoro- → 1-Chloro-1,1,3,3,3-pentafluoropropane

HRID 1108519

반응식

HRID 1108519 반응식
[Cl:1][C:2]([F:8])=[CH:3][C:4]([F:7])([F:6])[F:5].ClC(Cl)(F)CC(F)(F)[F:13].ClC(F)(F)CC(Cl)(F)F.ClC(Cl)=CC(F)(F)F.ClC(Cl)(Cl)CC(F)(F)F.ClC(Cl)(F)CC(Cl)(F)F.ClC(Cl)=CC(Cl)(F)F.ClC(Cl)(Cl)C=C(F)F.ClC(Cl)(Cl)CC(Cl)(F)F.ClC(Cl)(F)CC(Cl)(Cl)F.ClC(Cl)=CC(Cl)(Cl)F.ClC(F)=CC(Cl)(Cl)Cl.ClC(Cl)(Cl)CC(Cl)(Cl)F>>[Cl:1][C:2]([F:13])([F:8])[CH2:3][C:4]([F:7])([F:6])[F:5].[F:13][C:2]([F:8])=[CH:3][C:4]([F:7])([F:6])[F:5]

참가 물질

15

반응물 13

HCID 116662Propane, 1,1-dichloro-1,3,3,3-tetrafluoro-HCID 1202521-Propene, 1,1-dichloro-3,3,3-trifluoro-HCID 1389341,1,1-Trichloro-3,3,3-trifluoropropaneHCID 1501871,1,1,3-Tetrachloro-3,3-difluoropropaneHCID 27822971-Chloro-1,3,3,3-tetrafluoro-1-propeneHCID 53248871,1,3,3-Tetrachloro-3-fluoro-1-propeneHCID 110631011,3-Dichloro-1,1,3,3-tetrafluoropropaneHCID 14961191HCFC-231faHCID 187851923,3,3-Trichloro-1,1-difluoro-1-propeneHCID 232371951,1,3-Trichloro-3,3-difluoro-1-propeneHCID 23237200HCFC-232faHCID 232372011,1,3-Trichloro-1,3,3-trifluoropropaneHCID 543630711,3,3,3-Tetrachloro-1-fluoro-1-propene

생성물 2

HCID 680311-Chloro-1,1,3,3,3-pentafluoropropaneHCID 696471,1,3,3,3-Pentafluoropropene

실험 절차

Fluorinated saturated and olefinic compounds formed by contacting HCC-230fa with HF in step (1) can include, for example, 1-chloro-1,3,3,3-tetrafluoro-1-propene (HCFC-1224zb), 1,1-dichloro-1,3,3,3-tetrafluoropropane (HCFC-234fb), 1,3-dichloro-1,1,3,3-tetrafluoropropane (HCFC-234fa), 1,1-dichloro-3,3,3-trifluoro-1-propene (HCFC-1223za), 1,1,1-trichloro-3,3,3-trifluoropropane (HCFC-233fb), 1,1,3-trichloro-1,3,3-trifluoropropane (HCFC-233fa), 1,1,3-trichloro-3,3-difluoro-1-propene (HCFC-1222za), 3,3,3-trichloro-1,1-difluoro-1-propene (HCFC-1222zc), 1,1,1,3-tetrachloro-3,3-difluoropropane (HCFC-232fb), 1,1,3,3-tetrachloro-1,3-difluoropropane (HCFC-232fa), 1,1,3,3-tetrachloro-3-fluoro-1-propene (HCFC-1221za), 1,3,3,3-tetrachloro-1-fluoro-1-propene (HCFC-1221zb) and 1,1,1,3,3-pentachloro-3-fluoropropane (HCFC-231fa). In addition, small amounts of 1-chloro-1,1,3,3,3-pentafluoropropane (HCFC-235fa), and 1,1,3,3,3-pentafluoro-1-propene (HFC-1225zc) may also be formed, particularly if a catalyst is present. When CCl3CH2CCl3 is used as the starting material, small amounts of CCl3CH=CCl2 (another possible starting material) can be formed in addition to fluorinated compounds. The step (1) reaction is controlled to provide a fluorinated product which includes no more than about 40 mole percent HFC-236fa.

후처리

  1. customFluorinated saturated and olefinic compounds formed

출처 및 근거

ORD 기록
ord-20478bf9b6874d9993c2b0f5e4c96807
출처 데이터셋
uspto-grants-2000_05
특허 번호
US06066769

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