Triethylamine → 2-(5-Methyl-4-imidazolylmethylthio)ethyl N-[2-(5-methyl-4-imidazolylmethylthio)ethyl]dithiocarbamate

반응식

Cl.[CH3:2][C:3]1[NH:7][CH:6]=[N:5][C:4]=1[CH2:8][S:9][CH2:10][CH2:11][N:12]=[C:13]=[S:14].C(N(CC)CC)C.[CH3:22][C:23]1[NH:27][CH:26]=[N:25][C:24]=1[CH2:28][S:29][CH2:30][CH2:31][SH:32]>>[CH3:2][C:3]1[NH:7][CH:6]=[N:5][C:4]=1[CH2:8][S:9][CH2:10][CH2:11][NH:12][C:13](=[S:14])[S:32][CH2:31][CH2:30][S:29][CH2:28][C:24]1[N:25]=[CH:26][NH:27][C:23]=1[CH3:22]

참가 물질

반응물 3

HCID 8471Triethylamine

HCID 203874255-Methyl-4-(2-isothiocyanatoethylthiomethyl)imidazole hydrochloride

HCID 203874282-(5-Methyl-4-imidazolylmethylthio)ethanethiol

생성물 1

HCID 227653752-(5-Methyl-4-imidazolylmethylthio)ethyl N-[2-(5-methyl-4-imidazolylmethylthio)ethyl]dithiocarbamate

실험 절차

5-Methyl-4-(2-isothiocyanatoethylthiomethyl)imidazole hydrochloride may be treated with one equivalent of triethylamine and 2-(5-methyl-4-imidazolylmethylthio)ethanethiol according to the general procedure of Example 1(b) to give the title product.

출처 및 근거

ORD 기록: ord-271a40e5037c46a085dc0572a1566179
출처 데이터셋: uspto-grants-1978_10
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US04120972

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