Sodium Cyanide → Fenvalerate

HRID 1112605

반응식

HRID 1112605 반응식
[O:1]([C:8]1[CH:9]=[C:10]([CH:13]=[CH:14][CH:15]=1)[CH:11]=[O:12])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[Cl:16][C:17]1[CH:22]=[CH:21][C:20]([CH:23]([CH:27]([CH3:29])[CH3:28])[C:24](Cl)=[O:25])=[CH:19][CH:18]=1.[C-:30]#[N:31].[Na+]>O.CCCCCCC>[Cl:16][C:17]1[CH:22]=[CH:21][C:20]([CH:23]([CH:27]([CH3:29])[CH3:28])[C:24]([O:12][CH:11]([C:30]#[N:31])[C:10]2[CH:13]=[CH:14][CH:15]=[C:8]([O:1][C:2]3[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=3)[CH:9]=2)=[O:25])=[CH:19][CH:18]=1

참가 물질

6

반응물 3

HCID 8929Sodium Cyanide3회HCID 382843-PhenoxybenzaldehydeHCID 41780012-(4-Chlorophenyl)-3-methylbutanoyl chloride

생성물 1

HCID 3347Fenvalerate

시약·촉매·용매 2

HCID 962Water용매2회HCID 8900Heptane용매

실험 절차

A 500 ml round-bottomed flask equipped with a paddle stirrer was charged with 100 mmol of 3-phenoxybenzaldehyde, 100 mmol of 2-(4-chlorophenyl)-3-methylbutanoyl chloride, 120 mmol of sodium cyanide, 10 ml of water, and 200 ml of n-heptane. The molar ratio of water to sodium cyanide was 4.64, all NaCN being dissolved. The mixture thus formed was stirred and analysed. Table VI presents the yields and purities of the desired ester after the reaction time indicated.

후처리

  1. customA 500 ml round-bottomed flask equipped with a paddle stirrer
  2. customThe mixture thus formed
  3. customyields

출처 및 근거

ORD 기록
ord-dced4548778d4b5fbc68b4a165a71eaa
출처 데이터셋
uspto-grants-1978_10
특허 번호
US04123451

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