Dichloromethane → 4-(2-Diazo-acetyl)-piperidine-1-carboxylic acid benzyl ester

반응식

[CH2:1]([c:2]1[cH:3][cH:4][cH:5][cH:6][cH:7]1)[O:8][C:9](=[O:10])[N:11]1[CH2:12][CH2:13][CH:14]([C:17](=[O:18])[Cl:19])[CH2:15][CH2:16]1.[CH3:20][Si:21]([CH3:22])([CH3:23])[CH:24]=[N+:25]=[N-:26].[Cl:27][CH2:28][Cl:29]>>[CH2:1]([c:2]1[cH:3][cH:4][cH:5][cH:6][cH:7]1)[O:8][C:9](=[O:10])[N:11]1[CH2:12][CH2:13][CH:14]([C:17](=[O:18])[CH:24]=[N+:25]=[N-:26])[CH2:15][CH2:16]1

참가 물질

반응물 3

HCID 6344Dichloromethane

HCID 167693Trimethylsilyldiazomethane

HCID 2776270Benzyl 4-(chlorocarbonyl)piperidine-1-carboxylate

생성물 1

HCID 866488824-(2-Diazo-acetyl)-piperidine-1-carboxylic acid benzyl ester

출처 및 근거

ORD 기록: ord-a1984c27df7c42a49b02f1015ba350af
출처 데이터셋: Training data from https://doi.org/10.1039/C8SC04228D (7/10)
DOI: 10.1039/C8SC04228D

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