1-Iodohexane → Methyl 2-hydroxy-4-[7-(1-adamantyl)-6-hexyloxy-2-naphthyl]benzoate
반응식
[OH:1][C:2]1[CH:11]=[C:10]([C:12]2[CH:21]=[CH:20][C:19]3[C:14](=[CH:15][C:16]([C:23]45[CH2:32][CH:27]6[CH2:28][CH:29]([CH2:31][CH:25]([CH2:26]6)[CH2:24]4)[CH2:30]5)=[C:17]([OH:22])[CH:18]=3)[CH:13]=2)[CH:9]=[CH:8][C:3]=1[C:4]([O:6][CH3:7])=[O:5].I[CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH3:39]>>[OH:1][C:2]1[CH:11]=[C:10]([C:12]2[CH:21]=[CH:20][C:19]3[C:14](=[CH:15][C:16]([C:23]45[CH2:24][CH:25]6[CH2:26][CH:27]([CH2:28][CH:29]([CH2:31]6)[CH2:30]4)[CH2:32]5)=[C:17]([O:22][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH3:39])[CH:18]=3)[CH:13]=2)[CH:9]=[CH:8][C:3]=1[C:4]([O:6][CH3:7])=[O:5]참가 물질
3
실험 절차
Following the basic procedure of Example 11, by reacting 430 mg (1 mmol) of methyl 2-hydroxy-4-[7-(1-adamantyl)-6-hydroxy-2-naphthyl]benzoate with 180 μl (1.2 mmol) of 6-iodohexane, 280 mg (55%) of methyl 2-hydroxy-4-[7-(1-adamantyl)-6-hexyloxy-2-naphthyl]benzoate were obtained.
출처 및 근거
- ORD 기록
- ord-dbade7089fdb4aeda06e0dbd6d0e1ec8
- 출처 데이터셋
- uspto-grants-1998_03