Dichloromethane → 5-[(tert-Butyldiphenylsilyloxy)methyl]-5-[(tetradecanoyloxy)methyl]-tetrahydro-2-furanone

반응식

[CH2:53]1[O:54][CH2:55][CH2:56][CH2:57]1.[Cl:58][CH2:59][Cl:60].[O:42]=[Cr:43]([Cl:44])([O-:45])=[O:46].[OH:1][C:2]([CH2:3][O:4][C:5]([CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18])=[O:19])([CH2:20][CH:21]=[CH2:22])[CH2:23][O:24][Si:25]([c:26]1[cH:27][cH:28][cH:29][cH:30][cH:31]1)([c:32]1[cH:33][cH:34][cH:35][cH:36][cH:37]1)[C:38]([CH3:39])([CH3:40])[CH3:41].[nH+:47]1[cH:48][cH:49][cH:50][cH:51][cH:52]1>>[O:1]1[C:2]([CH2:3][O:4][C:5]([CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18])=[O:19])([CH2:23][O:24][Si:25]([c:26]2[cH:27][cH:28][cH:29][cH:30][cH:31]2)([c:32]2[cH:33][cH:34][cH:35][cH:36][cH:37]2)[C:38]([CH3:39])([CH3:40])[CH3:41])[CH2:20][CH2:21][C:22]1=[O:42]