Hydrogen Peroxide → 77456-46-3

HRID 1155067노트

반응식

HRID 1155067 반응식
[CH3:1][O:2][C:3]1[CH:8]=[CH:7][C:6]([C:9]2[NH:17][C:16]3[C:11](=[N:12][CH:13]=[N:14][CH:15]=3)[N:10]=2)=[C:5]([O:18][CH2:19][CH2:20][S:21][CH3:22])[CH:4]=1.OO.C(=O)([O-])[O-:26].[K+].[K+]>C(O)(=O)C.O>[CH3:1][O:2][C:3]1[CH:8]=[CH:7][C:6]([C:9]2[NH:17][C:16]3[C:11](=[N:12][CH:13]=[N:14][CH:15]=3)[N:10]=2)=[C:5]([O:18][CH2:19][CH2:20][S:21]([CH3:22])=[O:26])[CH:4]=1

참가 물질

6

반응물 3

HCID 784Hydrogen PeroxideHCID 11430Potassium CarbonateHCID 30599141H-Purine, 8-(4-methoxy-2-(2-(methylthio)ethoxy)phenyl)-

생성물 1

HCID 305991577456-46-3

시약·촉매·용매 2

HCID 176Acetic Acid용매HCID 962Water용매

실험 절차

One gram of 8-[4-methoxy-2-(2-methylmercapto-ethoxy)phenyl]purine was dissolved in 10 ml of glacial acetic acid and mixed with 0.5 ml of 30% hydrogen peroxide. After standing for 3.5 hours at room temperature, the reaction mixture was diluted with water and made alkaline by means of potassium carbonate. The precipitate was recrystallized from isopropanol/ethanol in a volume ratio of 1:1.

후처리

  1. customThe precipitate was recrystallized from isopropanol/ethanol in a volume ratio of 1:1

출처 및 근거

ORD 기록
ord-04319949ba4f417380491cc005a4805d
출처 데이터셋
uspto-grants-1981_11
특허 번호
US04299834

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