참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Formaldehyde | HCID 712 | — |
| 반응물 | Dimethylformamide | HCID 6228 | — |
| 반응물 | 2-Nitrotoluene | HCID 6944 | — |
| 반응물 | Potassium Hydroxide | HCID 14797 | — |
| 용매 | Water | HCID 962 | — |
| 생성물 | 2-Nitrotoluene | HCID 6944 | — |
| 생성물 | 1-(2-Nitrophenyl)ethanol | HCID 97851 | — |
반응 단계
A mixture of 137 g (1 mole) of o-nitrotoluene, 120 g of paraformaldehyde, 34 g of potassium hydroxide and 500 ml of dimethyl formamide containing 0.7% by weight of water is stirred at 30° C. for 1.5 hours and then at 55° C. for 1 hour. The reaction mixture is processed as described in Example 1 to obtain 35 g of o-nitrophenylethanol, 20 g of o-nitrotoluene and 35 g of bis-methylol compounds. The bis-methylol compounds were identified by gas chromatographical mass spectrum (GCMS) analysis.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US04299992 |
|---|
| 출처 데이터셋 | uspto-grants-1981_11 |
|---|
| ORD ID | ord-8656c1d09c184b4da34a03225db3f9b9 |
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| 출처 메모 | uspto-grants-1981_11 |
|---|
